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  Chem. Eur. J. 2002, 8, 94-101

Chem. Commun. 2005, 2540-2548

New J. Chem. 2007, 31, 800-817

 

  

 

Chem. 2017, 3, 92-109

 

 

2017

S. Jha, F. Ramadori, S. Quarta, A. Biasiolo, E. Fabris, P. Baldan, G. Guarino, M. Ruvoletto, G. Villano, C. Turato, A. Gotta, F. Mancin, P. Pontisso, P. Scrimin, “Binding and Uptake into Human Hepatocellular Carcinoma Cells of Peptide-Functionalized Gold Nanoparticles” Bioconj. Chem., 2017, 28, 222-229.

C. Sissi, L. Dovigo, M.L. Greco, A. Ciancetta, S. Moro, J.W. Trzcinski, F. Mancin, P. Rossi, G. Spalluto, P. Tecilla, “Conjugates between minor groove binders and Zn(II)-tach complexes: Synthesis, characterization, and interaction with plasmid DNA”, Tetrahedorn, 2017, 73 , 3014-3024.

 

2016

T. Gonzalez-Garcia, S. Fernandez, E. Lubian, F. Mancin, M. Ferrero, “Preparation of ORMOSIL nanoparticles conjugated with vitamin D-3 analogues and their biological evaluation” RSC Advances, 2016, 6, 31840-31849.

L. Brigo, A. Pistore, L. Bau, M. Arduini, F. Mancin, G. Brusatin, “Natively porous films as halide anion fluorescence optical sensors” Thin Solid Films, 2016, 600, 53-58.

T. Gonzalez-Garcia, T.  Margola, A. Silvagni, F. Mancin, F. Rastrelli “Chromatographic NMR Spectroscopy with Hollow Silica Spheres” Angew. Chem. Int. Ed., 2016, 55, 2733-2737

F. Mancin, L. J. Prins, P. Pengo, L. Pasquato, P. Tecilla, P. Scrimin, “Hydrolytic Metallo-Nanozymes: From Micelles and Vesicles to Gold Nanoparticles” Molecules, 2016, 21, 1014-1032.

S. Bonacchi, A. Cantelli, G. Battistelli, G. Guidetti, M. Calvaresi, J. Manzi, L. Gabrielli, F. Ramadori, A.  Gambarin, F. Mancin, M. Montalti “Photoswitchable NIR-Emitting Gold Nanoparticles” Angew. Chem. Int. Ed., 2016, 55, 11064-11068.

M. Diez-Castellnou, M. V. Salvia, S. Springhetti, F. Rastrelli, F. Mancin, “Nanoparticle-Assisted Affinity NMR Spectroscopy: High Sensitivity Detection and Identification of Organic Molecules” Chem Eur. J., 2016, 22, 16955-16961.

L. Gabrielli, F. Mancin, “Minimal Self-lmmolative Probe for Multimodal Fluoride DetectionJ. Org. Chem., 2016, 81, 10715-10720.

 

2011-2015

M.-V.Salvia, F. Ramadori, S. Springhetti, M. Diez-Castellnou, B. Perrone, F. Rastrelli, F. Mancin “Nanoparticle-Assisted NMR Detection of Organic Anions: From Chemosensing to Chromatography” J. Am. Chem. Soc., 2015, 137, 886−892.

F. Moret, F. Selvestrel, E. Lubian, M. Mognato, L. Celotti, F. Mancin, E. Reddi  “PEGylation of ORMOSIL nanoparticles differently modulates the in vitro toxicity toward human lung cells”, Arch. Toxicol. 2015, 89,  607-620.

A. Piserchia, M. Zerbetto, M.-V. Salvia, G. Salassa, L. Gabrielli,  F. Mancin, F. Rastrelli,  D. Frezzato “Conformational Mobility in Monolayer-Protected Nanoparticles: From Torsional Free Energy Profiles to NMR Relaxation”,  J. Phys. Chem. A, 2015, 20100-20110.

M.-V.Salvia, G. Salassa, F. Rastrelli, F. Mancin “Turning Supramolecular Receptors into Chemosensors by Nanoparticle-Assisted "NMR Chemosensing"” J. Am. Chem. Soc., 2015, 137, 11399-11406.

C. Fedeli, D. Segat, R. Tavano, L. Bubacco, G. De Franceschi, P. P. de Laureto, E. Lubian, F. Selvestrel, F. Mancin, E. Papini “The functional dissection of the plasma corona of SiO2-NPs spots histidine rich glycoprotein as a major player able to hamper nanoparticle capture by macrophages” Nanoscale, 2015, 7, 17710-17728.

M. Diez-Castellnou, F. Mancin, P. Scrimin “Efficient Phosphodiester Cleaving Nanozymes Resulting from Multivalency and Local Medium Polarity ControlJ. Am. Chem. Soc., 2014, 136, 1158-1161.

C. Fedeli, D. Segat, R. Tavano, G. De Franceschi, P. P. de Laureto, E. Lubian, F. Selvestrel, F. Mancin, E. Papini, "Variations of the corona HDL: albumin ratio determine distinct effects of amorphous SiO2 nanoparticles on monocytes and macrophages in serum", Nanomedicine, 2014, 9, 2481-249

C. Fede, C. Millino, B. Pacchioni, B. Celegato, C. Compagnin, P. Martini, F. Selvestrel, F. Mancin, L. Celotti, G. Lanfranchi, M. Mognato, S. Cagnin, "Altered Gene Transcription in Human Cells Treated with Ludox (R) Silica Nanoparticles", Int. J. Environ. Res. Pub. Health, 2014, 11, 8867-8890.

P. Salice, A. Gambarin, N. Daldosso, F. Mancin, E. Menna, "Noncovalent Interaction between Single-Walled Carbon Nanotubes and Pyrene-Functionalized Gold Nanoparticles in Water-Soluble Nanohybrids", J. Phys. Chem. C, 2014, 118, 27028-27038.

E. Longo, A. Orlandin, F. Mancin, P. Scrimin, A. Moretto, “Reversible Chirality Control in Peptide-Functionalized Gold NanoparticlesACS Nano, 2013, 7, 9933-9939

R. Bonomi, G. Saielli, P. Scrimin, F. Mancin, “An experimental and theoretical study of the mechanism of cleavage of an RNA-model phosphate diester by mononuclear Zn(II) complexes” Supramolecular Chemistry, 2013, 25, 665-671.

B. Perrone, S. Springhetti, F. Ramadori, F. Rastrelli, F. Mancin, “"NMR Chemosensing" Using Monolayer-Protected Nanoparticles as Receptors”J. Am. Chem. Soc., 2013, 135 , 11768-11771

C. Fedeli, F. Selvestrel, R. Tavano, D. Segat, F. Mancin, E. Papini, “Catastrophic inflammatory death of monocytes and macrophages by overtaking of a critical dose of endocytosed synthetic amorphous silica nanoparticles/serum protein complexes” Nanomedicine, 2013, 8, 1101-1126

F. Mancin, L. J. Prins, P. Scrimin, “Catalysis on gold-nanoparticle-passivating monolayers” Curr. Opin. Colloid Interface Sci. 2013, 18, 61-69

F. Selvestrel,  F. Moret, C.Fedeli, J. H. Woodhams, S. Zanini, I. Rio Echevarria, L. Baù, F. Rastrelli, C. Compagnin, E. Reddi, R. Tavano, D. Segat, E. Papini, A. Mackenzie, M. Bovis, E. Yaghini, A. MacRobert, G. Fracasso, A. Boscaini, M. Colombatti,  F. Mancin, “Targeted delivery of  photosensitizers: efficacy and selectivity issues revealed by multifunctional ORMOSIL nanovectors in cellular systems” Nanoscale, 2013, 5, 6106-6116.

S. Fallarini, T .Paoletti, C. O. Battaglini, P. Ronchi, L. Lay, R. Bonomi, S. Jha, F. Mancin, P. Scrimin, G. Lombardi, “Factors affecting T cell responses induced by fully synthetic glyco-gold-nanoparticles”  Nanoscale, 2013, 5 , 390-400.

 C. Fede, F. Selvestrel, C. Compagnin, M. Mognato, F. Mancin, E. Reddi, L. Celotti, “The toxicity outcome of silica nanoparticles (Ludox) is influenced by testing techniques and treatment modalities” Anal. Bioanal. Chem., 2012, 404 , 1789-1802.

L. Bau, F. Selvestrel, M. Arduini, I. Zamparo, C. Lodovichi, F. Mancin, “A Cell-Penetrating Ratiometric Nanoprobe for Intracellular Chloride” Org. Lett., 2012, 14, 2984-2987.

F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato “Progress in Artificial Metallonucleases” Chem. Commun. 2012, 48, 5545-55559.

G. Guarino, F. Rastrelli, P. Scrimin, F. Mancin, “Lanthanide-Based NMR: A Tool To Investigate Component Distribution in Mixed-Monolayer-Protected Nanoparticles”  J. Am. Chem. Soc., 2012, 134 , 7200–7203.

G. Guarino, F. Rastrelli, F. Mancin “Mapping the nanoparticle-coating monolayer with NMR pseudocontact shifts” Chem. Commun. 2012, 48 ,1523-1525.

P. Dolcet, M. Casarin, C. Maccato, L. Bovo, G. Ischia, S. Gialanella, F. Mancin, E. Tondello, S. Gross “Miniemulsions as chemical nanoreactors for the room temperature synthesis of inorganic crystalline nanostructures: ZnO colloids”,  J. Mat. Chem. 2012, 22, 1620-1626.

L. Brigo, G. Grenci, L. Bau, A. Carpentiero, F. Mancin, F. Romanato, M. Tormen, M. Guglielmi, G. Brusatin “Hybrid porous resist with sensing functionalityMicroelectronic Engineering, 2011, 88, 1913-1916

D. Segat, R. Tavano, M. Donini, F. Selvestrel, I. Rio-Echevarria, M. Rojnik, P. Kocbek, J. Kos, S. Iratni, D. Sheglmann, F. Mancin, S. Dusi, E. Papini “Proinflammatory effects of bare and PEGylated ORMOSIL-, PLGA- and SUV-NPs on monocytes and PMNs and their modulation by f-MLP” Nanomedicine, 2011, 6, 1027-1046

I. M. Rio-Echevarria , R. Tavano, V. Causin,  E. Papini, F. Mancin,  A. Moretto “Water-Soluble Peptide-Coated Nanoparticles: Control of the Helix Structure and Enhanced Differential Binding to Immune Cells”  J. Am. Chem. Soc. 2011, 133, 8-11.

L. Bau, P. Tecilla, F. Mancin “Sensing with fluorescent nanoparticles” Nanoscale , 2011, 3, 121-133.

 

2006-2010

R. Tavano, D. Segat, E. Reddi, J. Kos, M. Rojnik, P. Kocbek, S. Iratni, D. Scheglmann, M. Colucci, I. M. Rio Echevarria, F. Selvestrel, F. Mancin, E. Papini “Procoagulant properties of bare and highly-PEGylated vinyl-modified silica nanoparticles”, Nanomedicine, 2010, 5, 881-896.

R. Bonomi, P. Scrimin, F. Mancin “Phosphate diesters cleavage mediated by Ce(IV) complexes self-assembled on gold nanoparticles”, Org. Biomol. Chem., 2010, 8, 2622-2626.

V. Lombardo, R. Bonomi, C. Sissi, F. Mancin “Phosphate diesters and DNA hydrolysis by dinuclear Zn(II) complexes featuringa disulfide bridge and H-bond donors” Tetrahedron, 2010, 66, 2189–2195.

I. M. Rio-Echevarria, F. Selvestrel, D. Segat, G. Guarino, R. Tavano, V. Causin, E. Reddi, E. Papini, and F. Mancin “Highly PEGylated silica nanoparticles: “ready to use” stealth functional nanocarriers”, J. Mat. Chem. 2010, 20, 2780-2787

L. Baù, B. BarBtova, M. Arduini, F. Mancin “Surfactant-free synthesis of mesoporous and hollow silica nanoparticles with an inorganic template” Chem. Commun., 2009, 7584-7586.

F. Rastrelli, S. Jha, F. Mancin “Seeing through Macromolecules: T2-Filtered NMR for the Purity Assay of Functionalized Nanosystems and the Screening of Biofluids” J. Am. Chem. Soc. 2009, 131, 14222–14224.

R. Bonomi, G. Saielli, U. Tonellato, P. Scrimin, F. Mancin “Insights on Nuclease Mechanism: The Role of Proximal Ammonium Group on Phosphate Esters Cleavage” J. Am. Chem. Soc. 2009, 131, 11278- 11279.

C. Compagnin, L. Bau, M. Mognato, L. Celotti, G. Miotto, M. Arduini, F. Moret, C. Fede, F. Selvestrel, I. M. Rio-Echevarria, F. Mancin, E. Reddi “The cellular uptake of meta-tetra (hydroxyphenyl)chlorin entrapped in organically modified silica nanoparticles is mediated by serum proteins” Nanotechol. 2009, 20, 345101.

L. J. Prins, F., Mancin, P. Scrimin “Multivalent Cooperative Catalysts” Curr. Org. Chem. 2009, 13, 1050-1064.

F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato “Amphiphilic metalloaggregates: Catalysis, transport, and sensing” Coord. Chem. Rev. 2009, 253, 2150-2165.

R. Bonomi, F. Selvestrel, V.  Lombardo, C. Sissi, S. Polizzi, F. Mancin, U. Tonellato, P. Scrimin “Phosphate Diester and DNA Hydrolysis by a Multivalent, Nanoparticle-Based Catalyst” J. Am. Chem. Soc. 2008, 130, 15744-15745.

F. Manea, C. Bindoli, S. Fallarini, G. Lomabardi, L. Polito, L. Lay, R. Bonomi, F. Mancin, P. Scrimin “Multivalent, Saccharide-Functionalized Gold Nanoparticles as Fully Synthetic Analogs of Type A Neisseria meningitidis Antigens” Adv. Mater. 2008, 20, 4348-4352.

S. Bonacchi, E. Rampazzo, M. Montalti, L. Prodi, N. Zaccheroni, F. Mancin, P. Teolato “Amplified fluorescence response of chemosensors grafted onto silica nanoparticles” Langmuir 2008, 24, 8387-8392

F. Mancin, P. Tecilla “Zinc(II) complexes as hydrolytic catalysts of phosphate diester cleavage: from model substrates to nucleic acids” New J. Chem. 2007, 31, 800-817.

M. Arduini, F. Mancin, P. Tecilla, U. Tonellato “Self-organized fluorescent nanosensors for ratiometric Pb2+ detection” Langmuir  2007, 23, 8632-8636.

M. Arduini, L. Armelao, S. Gross, F. Mancin, S. Marcuz, M. Montolli, C. Sada “Chemical optimisation of a sol-gel procedure for the development of fluorescence Cu(II) nanosensors” Appl. Surf. Sci., 2007, 253, 7178-7187.

M. Livieri, F. Mancin, G. Saielli, J. Chin, U. Tonellato “Mimicking enzymes: cooperation between organic functional groups and metal ions in the cleavage of phosphate diesters” Chem Eur. J., 2007, 8, 2246-2256

P. Teolato, E. Rampazzo, M. Arduini, F. Mancin, P. Tecilla, U. Tonellato “Silica nanoparticles for fluorescence sensing of Zn(II): exploring the covalent strategy” Chem Eur. J., 2007, 8, 2238-2245.

M. Arduini, E. Rampazzo, F. Mancin, P. Tecilla, U. Tonellato “Template Assisted Self-Organized Chemosensors” Inorganica Chimica Acta, 2007, 360, 721-727.

L. Bertazza, L. Celotti, G. Fabbrini, M. A. Loi, M. Maggini, F. Mancin, S. Marcuz, E. Menna, M. Muccini U. Tonellato “Cell penetrating silica nanoparticles doped with two-photon absorbing fluorophores” Tetrahedron, 2006, 62, 10434-10440.

M. Montalti, L. Prodi, N. Zaccheroni, G. Battistini, S. Marcuz, F. Mancin, E. Rampazzo, U. Tonellato “Size effect on the fluorescence properties of dansyl-doped silica nanoparticles” Langmuir, 2006, 22, 5877-5881.

F. Mancin, E. Rampazzo, P. Tecilla, U. Tonellato “Self-Assembled Fluorescent Chemosensors” Chem. Eur. J. 2006, 12, 1844-1854.

 

2005-2000

M. Arduini, S. Marcuz, M. Montolli, E. Rampazzo, F. Mancin, S. Gross, L. Armelao, P. Tecilla, U. Tonellato “Turning Fluorescent Dyes into Cu(II) Nanosensors” Langmuir, 2005, 21, 9314-9321

E. Rampazzo, E. Brasola, S. Marcuz, F. Mancin, P.Tecilla, U. Tonellato “Surface modification of silica nanoparticles: a new strategy for the realization of self-organized fluorescence chemosensors ” J. Mat. Chem. 2005, 15, 2687-2696.

F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato “Artificial Nucleases” Chem. Commun. 2005, 2540 - 2548.

C. Sissi, F. Mancin, M. Gatos, M. Palumbo, P. Tecilla, U. Tonellato Efficient plasmid DNA cleavage by a mononuclear Cu(II) complex” Inorg. Chem. 2005, 44, 2310-2317.

M. Livieri, F. Mancin, U. Tonellato, J. Chin "Multiple functional group cooperation in phosphate diesters cleavage promoted by Zn(II) complexes" Chem. Commun. 2004, 2862 - 2863.

E. Boseggia, M. Gatos, L. Lucatello, F. Mancin, S. Moro, M. Palumbo, C. Sissi, P. Tecilla, U. Tonellato, G. Zagotto “Toward Efficient Zn(II)-based Artificial Nucleases” J. Am. Chem. Soc. 2004, 126, 4543-4549.

F. Mancin, E. Rampazzo, P. Tecilla, U. TonellatoDinuclear Metal Complexes Based on all cis 2,4,6-triamino-1,3,5- trihydroxycyclohexane as Catalysts of Phosphate Esters Cleavage” Eur. J. Org. Chem. 2004, 281-288.

J. Chin, F. Mancin, N. Thavarajah, D. Lee, A. Lough, D. S. Chung “Controlling Aza-Cope Rearrangement Reactions with Resonance Assisted Hydrogen Bonds” J. Am. Chem. Soc. 2003, 125, 15276-15277.

E. Brasola, F. Mancin, E. Rampazzo, P. Tecilla, U. Tonellato “A fluorescence nanosensor for Cu2+ on silica particles” Chem. Commun. 2003, 3026-3027.

M. Arduini, F. Felluga, F. Mancin, P. Rossi, P. Tecilla, U. Tonellato, N. Valentinuzzi "Aluminium fluorescence detection with a FRET amplified chemosensor" Chem. Commun. 2003, 1606 - 1607.

L. Bonfá, M. Gatos, F. Mancin, P. Tecilla, U. Tonellato "The Ligand Effect on the Hydrolytic Reactivity of Zn(II) Complexes Toward Phosphate Diesters" Inorg. Chem. 2003, 42, 3943-3949.

G. M. Bonora, S. Drioli, F. Felluga, F. Mancin, P. Rossi, P. Scrimin, P. Tecilla "Poly(ethylene glycol)-supported copper(II) triazacyclononane: an efficient, recoverable, and recyclable catalyst for the cleavage of a phosphodiester" Tetrahedron Lett. 2003, 44, 535-538.

F. De Riccardis, M. Di Filippo, D. Garrisi, I. Izzo, F. Mancin, L. Pascquato, P. Scrimin, P. Tecilla "An Artificial Ionophore Based on a Polyhydroxylated Steroid Dimer" Chem. Commun. 2002, 3066-3067.

F. Mancin, J. Chin "An Artificial Guanine that Binds Cytidine through the Cooperative Interaction of Metal Coordination and Hydrogen Bonding" J. Am. Chem. Soc. 2002, 124, 10946-10947.

L. Fabbrizzi, M. Licchelli, F. Mancin, M. Pizzeghello, G. Rabaioli., A. Taglietti., P. Tecilla, U. Tonellato "Fluorescence sensing of ionic analytes in water: From transition metal ions to Vitamin B13" Chem. Eur. J. 2002, 8, 94-101.

M. Beltramello, M. Gatos, F. Mancin, P. Tecilla, U. Tonellato "A new selective fluorescence chemosensor for Cu(II) in water" Tetrahedron Lett. 2001, 42, 9143-9146.

M. Berton, F. Mancin, G. Stocchero, P. Tecilla, U. Tonellato "Self-assembling in surfactant aggregates: An alternative way to the realization of fluorescence chemosensors for Cu(II) ions" Langmuir 2001, 17, 7521-7528.

M. Fanti, F. Mancin, P. Tecilla, U. Tonellato "Ester cleavage in reversed micelles by Cu(II) complexes of functionalized ligands" Langmuir 2000, 16, 10115-10122.

F. Mancin, P. Tecilla, U. Tonellato "Activation of oximic nucleophiles by coordination of transition metal ions" Eur. J. Org. Chem. 2000, 1045-1050.

F. Mancin, P. Tecilla, U. Tonellato "Metallomicelles made of Ni(II) and Zn(II) complexes of 2-pyridinealdoxime-based ligands as catalysts of the cleavage of carboxylic acid esters" Langmuir 2000, 16, 227-233.

L. Pascquato, F. Rancan, P. Scrimin, F. Mancin, C. Frigeri "N-Methylimidazole functionalized gold nanoparticles as catalysts for cleavage of carboxylic acid esters" Chem. Commun. 2000, 2253-2254.

C. Sissi, F. Mancin, M.Palumbo, P. Scrimin, P. Tecilla, U. Tonellato "DNA phosphodiester bond hydrolysis mediated by Cu(II) and Zn(II) complexes of 1,3,5-triaminocyclohexane derivatives" Nucleosides, Nucleotides & Nucleic Acids 2000, 19, 1265-1271.

 

1999-1997

P. Grandini, F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato "Exploiting the self assembly strategy for the design of selective Cu(II) ion chemosensors" Angew. Chem. Int. Ed. 1999, 38, 3061-3064.

F. Hampl, F. Liska, F. Mancin, P. Tecilla, U. Tonellato "Metallomicelles made of Ni(II) complexes of lipophilic 2-pyridineketoximes as powerful catalysts of the cleavage of carboxylic acid esters" Langmuir 1999, 15, 405-412.

F. Bertoncin, F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato "Kinetic amplification of the enantioselective cleavage of alpha-amino acid esters by metallomicelles" Langmuir 1998, 14, 975-978.

M.C. Cleij, F. Mancin, P. Scrimin, P. Tecilla, U. Tonellato "Enantioselective ester cleavage of a-amino esters by Cu(II) complexes of chiral diamino alcols in acqueus surfactants solutions" Tetrahedron 1997, 53, 357-368.

  

 

Università di Padova Dipartimento di Chimica Organica