Publications

Carlotto, S., Babetto, L., Rancan, M., Bottaro, G., Casarin, M., and Armelao, L. (2023). How to get deeper insights into the optical properties of lanthanide systems: A computational protocol from ligand to complexes. Pure and Applied Chemistry. 10.1515/pac-2023-0118.

De Marco, R., Giuso, V., Achard, T., Rancan, M., Baron, M., Armelao, L., Mauro, M., Bellemin-Laponnaz, S., and Tubaro, C. (2023). Exploring the Coordination Properties of Phosphonium-Functionalized N-Heterocyclic Carbenes Towards Gold. European Journal of Inorganic Chemistry. 10.1002/ejic.202300184.

Candela, V., Cavallini, C., Gasparrini, C., Armelao, L., Candeloro, V., Dalla Palma, M., Fadone, M., Marcuzzi, D., Pavei, M., Pepato, A., Duteil, P.D., Rancan, M., Rizzolo, A., Sartori, E., Segalini, B., Serianni, G., Spolaore, M., Zorzi, F., and Sonato, P. (2023). Investigations on Caesium Dispersion and Molybdenum Coating on SPIDER Components. Materials. 10.3390/ma16010206.

Biffi, C.A., Fiocchi, J., Rancan, M., Gambaro, S., Cirisano, F., Armelao, L., and Tuissi, A. (2023). Ultrashort Laser Texturing of Superelastic NiTi: Effect of Laser Power and Scanning Speed on Surface Morphology, Composition and Wettability. Metals. 10.3390/met13020381.

Bergamini, L., Sangiorgi, N., Gondolini, A., Rancan, M., Bottaro, G., Armelao, L., and Sanson, A. (2023). CsPbBr_3/platinum and CsPbBr₃/graphite hybrid photoelectrodes for carbon dioxide conversion to oxalic acid. Solar Energy. 10.1016/j.solener.2023.02.043.

Bellucci, L., Giordano, L., Carlotto, S., Poneti, G., Rancan, M., Samaritani, S., Armelao, L., and Labella, L. (2023). Heterometallic [Ln(hfac)₃Cu(acac)₂] complexes with late 4f ions. Inorganica Chimica Acta.10.1016/j.ica.2023.121665.

Bellucci, L., Fioravanti, L., Armelao, L., Bottaro, G., Marchetti, F., Pineider, F., Poneti, G., Samaritani, S., and Labella, L. (2023). Size Selectivity in Heterolanthanide Molecular Complexes with a Ditopic Ligand. Chemistry - A European Journal. 10.1002/chem.202202823

Bellucci, L., Carlotto, S., Bottaro, G., Babetto, L., Labella, L., Gallo, E., Marchetti, F., Samaritani, S., and Armelao, L. (2023). Competing excitation paths in luminescent heterobimetallic Ln-Al complexes: Unraveling interactions via experimental and theoretical investigations. iScience. 10.1016/j.isci.2023.106614.

Battiston, S., Fiameni, S., Fasolin, S., Barison, S., and Armelao, L. (2023). Life cycle environmental impact assessment of lab-scale preparation of porous alumina pellets as substrate for hydrogen separation metal layer-based membranes. International Journal of Life Cycle Assessment. 10.1007/s11367-023-02179-5.

Bartolomé, E., Ferrari, L., Sedona, F., Arauzo, A., Rubín, J., Luzón, J., Herrero-Albillos, J., Panighel, M., Mugarza, A., Rancan, M., Sambi, M., Armelao, L., Bartolomé, J., Bartolomé F. (2023). Surface Deposition Induced Reduction of the Ground State Spin in Cr₁₀ Wheel. Advanced Materials Interfaces. 10.1002/admi.202300146.

Carlotto, S., Armelao, L., and Rancan, M. (2022). Helicate versus Mesocate in Quadruple-Stranded Lanthanide Cages: A Computational Insight. International Journal of Molecular Sciences. 10.3390/ijms231810619.

Stoppa, V., Battistel, E., Baron, M., Sgarbossa, P., Biffis, A., Bottaro, G., Armelao, L., and Tubaro, C. (2022). Dinuclear gold(I) Complexes with Bidentate NHC Ligands as Precursors for Alkynyl Complexes via Mechanochemistry. Molecules. 10.3390/molecules27134317.

Rubín, J., Arauzo, A., Bartolomé, E., Sedona, F., Rancan, M., Armelao, L., Luzón, J., Guidi, T., Garlatti, E., Wilhelm, F., Rogalev, A., Amann, A., Spagna, S., Bartolomé , J., and Bartolomé, F. et al. (2022). Origin of the Unusual Ground-State Spin S = 9 in a Cr₁₀ Single-Molecule Magnet. Journal of the American Chemical Society. 10.1021/jacs.2c05453.

Rancan, M., Tessarolo, J., Carlotto, A., Carlotto, S., Rando, M., Barchi, L., Bolognesi, E., Seraglia, R., Bottaro, G., Casarin, M., Clever, G. and Armelao L. (2022). Adaptive helicity and chiral recognition in bright europium quadruple-stranded helicates induced by host-guest interaction. Cell Reports Physical Science. 10.1016/j.xcrp.2021.100692.

Rancan, M., Rando, M., Bosi, L., Carlotto, A., Seraglia, R., Tessarolo, J., Carlotto, S., Clever, G.H., and Armelao, L. (2022). Dynamic lanthanide exchange between quadruple-stranded cages: the effect of ionic radius differences on kinetics and thermodynamics. Inorganic Chemistry Frontiers. 10.1039/d2qi00641c.

Orlandin, A., Guryanov, I., Ferrazzano, L., Biondi, B., Biscaglia, F., Storti, C., Rancan, M., Formaggio, F., Ricci, A., and Cabri, W. (2022). Carbodiimide-Mediated Beckmann Rearrangement of Oxyma-B as a Side Reaction in Peptide Synthesis. Molecules. 10.3390/molecules27134235.

Longhi, A., Baron, M., Rancan, M., Bottaro, G., Orian, L., Graiff, C., Roverso, M., Menegazzo, I., Armelao, L., Bogialli, S., Tubaro, C. (2022). Silver(I) and gold(I) complexes with bitriazole-based N-heterocyclic carbene ligand: Solid state features and behaviour in solution. Applied Organometallic Chemistry. 10.1002/aoc.6764.

Gabbani, A., Campo, G., Bonanni, V., Van Rhee, P., Bottaro, G., De Julián Fernández, C., Bello, V., Fantechi, E., Biccari, F., Gurioli, M., Armelao, L. Sangregorio, C., Mattei, G., Christianen, P., and Pineider F. (2022). High Magnetic Field Magneto-optics on Plasmonic Silica-Embedded Silver Nanoparticles. Journal of Physical Chemistry C. 10.1021/acs.jpcc.1c09900.

Fioravanti, L., Bellucci, L., Armelao, L., Bottaro, G., Marchetti, F., Pineider, F., Poneti, G., Samaritani, S., and Labella, L. (2022). Stoichiometrically Controlled Assembly of Lanthanide Molecular Complexes of the Heteroditopic Divergent Ligand 4′-(4-Pyridyl)-2,2′:6′,2″-terpyridine N-Oxide in Hypodentate or Bridging Coordination Modes. Structural, Magnetic, and Photoluminescence Studies. Inorganic Chemistry. 10.1021/acs.inorgchem.1c02809.

Fasolin, S., Barison, S., Agresti, F., Battiston, S., Fiameni, S., Isopi, J., and Armelao, L. (2022). New Sustainable Multilayered Membranes Based on ZrVTi for Hydrogen Purification. Membranes. 10.3390/membranes12070722.

Bevilacqua, M., Giuso, V., Rancan, M., Armelao, L., Graiff, C., Baratta, W., Di Marco, V., and Biffis, A. (2022). Coordination Chemistry of Ir with Chelating Ligands Containing a Xanthine-Derived, Protic N-Heterocyclic Carbene (NHC) Moiety. European Journal of Inorganic Chemistry. 10.1002/ejic.202200484.

Bartoletti, A., Gondolini, A., Sangiorgi, N., Aramini, M., Ardit, M., Rancan, M., Armelao, L., Kondrat, S.A., and Sanson, A. (2022). Identification of structural changes in CaCu₃Ti₄O₁₂ on high energy ball milling and their effect on photocatalytic performance. Catalysis Science and Technology. 10.1039/d2cy01299e.

F. Mian, G. Bottaro, Z. Wang, Y.M. Yiu, M. Rancan, T.K. Sham, L. Armelao Chromium doped ZnGa₂O₄ thin films: An X-ray absorption near edge structure (XANES) and X-ray excited optical luminesce (XEOL) study Appl. Surf. Sci. 2021, 151896.

N. Comisso, L. Armelao, S. Cattarin, S. Fasolin, L. Mattarozzi, M. Musiani, M. Rancan, L. Vázquez-Gómez, E. Verlato Oxide-oxide galvanic displacement reactions: Effect of the concentration of the ions released by the sacrificial oxide J. Electroanal. Chem. 2021, 896, art. no. 115199.

C. Cometto, A. Ugolotti, E. Grazietti, A. Moretto, G. Bottaro, L. Armelao, C. Di Valentin, L. Calvillo, G. Granozzi Copper single-atoms embedded in 2D graphitic carbon nitride for the CO₂ reduction npj 2D Mater. Appl. 2021, 5, art. no. 63.

S. Battiston, F. Montagner, V. Zin, S. Barison, A. Fiorese, A. Gionda, M. Rancan, F. Sordello, M. Minella, C.A. Biffi, J. Fiocchi, A. Tuissi, L. Armelao Vacuum Thermal Treatments for Surface Engineering of Selective Laser Melted Ti6Al4V Alloy J. Mat. Eng. Perf. 2021, 30, 6874.

L. Bellucci, G. Bottaro, L. Labella, F. Marchetti, S. Samaritani, D. Belli Dell'amico, L. Armelao 1d-zigzag Eu³⁺/Tb³⁺ coordination chains as luminescent ratiometric thermometers endowed with multicolor emission Materials 2021, 14, art. no. 6445.

S. Mostoni, M. D'Arienzo, B. Di Credico, L. Armelao, M. Rancan, S. Dirè, E. Callone, R. Donetti, A. Susanna, R. Scotti Design of a Zn Single-Site Curing Activator for a More Sustainable Sulfur Cross-Link Formation in Rubber Ind. Eng. Chem. Res. 2021, 60, 10180.

S. Carlotto, L. Babetto, M. Bortolus, A. Carlotto, M. Rancan, G. Bottaro, L. Armelao, D. Carbonera, M. Casarin Nature of the Ligand-Centered Triplet State in Gd³⁺ β-Diketonate Complexes as Revealed by Time-Resolved EPR Spectroscopy and DFT Calculations Inorg. Chem. 2021, 60,15141.

B. Biondi, R. Cardena, A. Bisello, R. Schiesari, L. Cerveson, M. Facci, M. Rancan, F. Formaggio, S. Santi. Flat, Ferrocenyl-Conjugated Peptides: A Combined Electrochemical and Spectroscopic Study ChemElectroChem 2021, 8, 2693.

M.W. Murphy, L. Bovo, G. Bottaro, L. Armelao, T.K. Sham Electronic and relating behavior of Mn-doped ZnO nanostructures: An x-ray absorption spectroscopy study AIP Advances 2021, 11, art. no. 06502.

M. De Muri, A. Rizzolo, E. Sartori, S. Cristofaro, M. Barbisan, M. Fadone, D. Ravarotto, R. Rizzieri, R. Capobianco, P. Cinetto, B. Laterza, F. Rossetto, M. Rancan, L. Armelao, C. Taliercio, G. Serianni, D. Marcuzzi.

SPIDER Cs Ovens functional tests Fusion Eng. Design. 2021, 167, 11233.

L. Poggini, A. Lunghi, A. Collauto, A. Barbon, L. Armelao, A. Magnani, C. Caneschi, F. Totti, L. Sorace, M. Mannini Chemisorption of nitronyl-nitroxide radicals on gold surface: An assessment of morphology, exchange interaction and decoherence time Nanoscale, 2021, 13, 7613.

M. Baron, M., Rancan, L., Armelao, C., Tubaro. Quantitative Selection of the Axially Chiral Conformation in a Flexible Dinuclear Gold(I) di(N-Heterocyclic Carbene) Complex via Chlorine Oxidative Addition J. Chem. Cryst. 2021, 51, 175.

L. Babetto, S. Carlotto, A. Carlotto, M. Rancan, G. Bottaro, L. Armelao, M. Casarin Multireference Ab Initio Investigation on Ground and Low-Lying Excited States: Systematic Evaluation of J-J Mixing in a Eu³⁺ Luminescent Complex Inorg. Chem. 2021, 60, 1, 315.

A. Biffs, M. Baron, C. Tubaro, M. Rancan, L. Armelao, A. Marchenko, G. Koidan, A. N. Hurieva, A. Kostyuk Gold(I) complexes with multifunctional phosphane ligands: Synthesis and catalysis Inorg. Chim. Acta 2021, 517, 120218.

S. Fiameni, S. Battiston, V. Castellani, S. Barison, L. Armelao Implementing sustainability in laboratory activities: A case study on aluminum titanium

nitride based thin film magnetron sputtering deposition onto commercial laminated steel J. Clean. Prod. 2021, 285, 124869.

N. Comisso, L. Armelao, S. Cattarin, S. Fasolin , L. Mattarozzi, M. Musiani, M. Rancan, L. Vázquez-Gómez, E. Verlato Deposition of FeOOH layers onto porous PbO₂ by galvanic displacement and their use as electrocatalysts for oxygen evolution reaction J. Electrochem. Soc. 2021, 880, 114844.

L. Bellucci, G. Bottaro, L. Labella, V. Causin, F. Marchetti, S. Samaritani, D. Belli Dell'Amico, L. Armelao Composition-Thermometric Properties Correlations in Homodinuclear Eu³⁺ Luminescent Complexes Inorg. Chem. 2020, 59, 18156.

L. Babetto, S. Carlotto, A. Carlotto, M. Rancan, G. Bottaro, L. Armelao, M. Casarin Antenna triplet DFT calculations to drive the design of luminescent Ln³⁺ complexes Dalton Trans., 2020, 49, 14556.

N. Comisso, M. Rancan, L. Armelao, S. Barison, S. Cattarin, P. Guerriero, L. Mattarozzi, M. Musiani, L. Vázquez-Gómez, E. Verlato Investigation on the oxide-oxide galvanic displacement reactions employed in the preparation of electrocatalytic layers Electrochimica Acta 2020, 341, 136056.

R. Zamboni, A. Zaltron, E. Izzo, G. Bottaro, D. Ferraro, C. Sada Opto-Microfluidic System for Absorbance Measurements in Lithium Niobate Device Applied to pH

Measurements Sensors 2020, 20, 5366.

S. Paria, E. Carletti, M. Marcon, A. Cherubini-Celli, A. Mazzanti, M. Rancan, L. Dell'Amico, M. Bonchio, X. Companyó Light-Triggered Catalytic Asymmetric Allylic Benzylation with Photogenerated C-Nucleophiles J. Org. Chem. 2020, 85, 6, 4463.

A. Carlotto, L. Babetto, S. Carlotto, M. Miozzi, R. Seraglia, M. Casarin, G. Bottaro , M. Rancan, L. Armelao Luminescent Thermometers: From a Library of Europium(III) β‐Diketonates to a General Model for Predicting the Thermometric Behaviour of Europium‐Based Coordination Systems ChemPhotoChem 2020, 4, 674.

J. De Bellis, L. Bellucci, G. Bottaro, L. Labella, F. Marchetti, S. Samaritani, D. Belli Dell'Amico, L. Armelao Single-crystal-to-single-crystal post-synthetic modifications of three-dimensional LOFs (Ln = Gd, Eu): a way to modulate their luminescence and thermometric properties Dalton Trans. 2020, 49, 6030.

M. Baron, M. Rancan, L. Armelao, C. Tubaro Quantitative Selection of the Axially Chiral Conformation in a Flexible Dinuclear Gold(I) di(N-Heterocyclic Carbene) Complex via Chlorine Oxidative Addition J. Chem. Cryst. 2020, doi.org/10.1007/s10870-020-00840-7.

A. Gimeno-Furio , L. Hernandez , S. Barison , F. Agresti , G. Bottaro , D. Cabaleiro , L. Doretti, S. Mancin Effects of Carbon Nanohorn Based Nanofluids Pool Boiling on Optical Properties and Wettability of Different Metal Surfaces Heat Transf. Eng. 2020, doi.org/10.1080/01457632.2020.1818407.

M. Rancan, G. Truccolo, A. Carlotto, S. Quici, L. Armelao A Zn(II) Metallocycle as Platform to Assemble a 1D + 1D → 1D Polyrotaxane via π···π Stacking of an Ancillary Ligand Inorganics 2019, 7, 137.

M. Zheng, F. Lamberti, L. Franco, E. Collini, I. Fortunati, G. Bottaro, G. Daniel, R. Sorrentino, A. Minotto, A. Kukovecz, E. Menna, S. Silvestrini, C. Durante, F. Cacialli, G. Meneghesso, M. Maggini, T. Gatti A film-forming graphene/diketopyrrolopyrrole covalent hybrid with far-red optical features: Evidence of photo-stability Synth. Met. 2019, 258, 116201.

M. Rancan, A. Carlotto , G. Bottaro, L. Armelao Effect of Coordinating Solvents on the Structure of Cu(II)-4,4′-bipyridine Coordination Polymers Inorganics 2019, 7, 103.

A. Longhi, M. Baron, M. Rancan, G. Bottaro , L. Armelao, P. Sgarbossa, C. Tubaro Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands Molecules 2019, 24, 2305.

G. Canu, G.Bottaro, M. T. Buscaglia, C. Costa, O. Condurache, L. Curecheriu, L. Mitoseriu, V. Buscaglia, L. Armelao Ferroelectric order driven Eu³⁺ photoluminescence in BaZr_xTi_1-xO₃ perovskite Sci. Rep. 2019, 9, 6441.

L. Bellucci, G. Bottaro, L. Labella, F. Marchetti, S. Samaritani, D. Belli Dell’Amico, L. Armelao Luminescent sequence-dependent materials through a step by step assembly of RE¹–1,4-benzendicarboxylate–RE² (RE^x = Y³⁺, Eu³⁺ and Tb³⁺) architectures on a silica surface J. Mat. Chem. C 2019, 7, 4415.

M. Monticelli, M. Baron , C. Tubaro, S. Bellemin-Laponnaz , Cl. Graiff , G. Bottaro , L. Armelao, L. Orian Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands ACS Omega 2019, 4, 4192.

S. Fasolin, M. Romano, S. Boldrini, A. Ferrario, M. Fabrizio, L. Armelao, S. Barison Single-step process to produce alumina supported hydroxy-sodalite zeolite membranes J. Mat. Sci., 2019, 54, 2049.

M. G. Pelizzo , A. J. Corso, E. Tessarolo, R. Böttger, R. Hübner, E. Napolitani, M. Bazzan, M. Rancan, L. Armelao, W. Jark, D. Eichert, A. Martucci Morphological and Functional Modifications of Optical Thin Films for Space Applications Irradiated with Low-Energy Helium Ions ACS Appl. Mater. Interfaces, 2018, 10, 34781.

L. Armelao, D. Belli Dell'amico, L. Bellucci, G. Bottaro, S. Ciattini, L. Labella, G. Manfroni, F. Marchetti, C. A. Mattei, S. Samaritani Homodinuclear Lanthanide Complexes with the Divergent Heterotopic 4,4’‐bipyridine‐N‐oxide (bipyMO) Ligand Eur. J. Inorg. Chem., 2018, 40, 4421.

G. Truccolo, Z. Tessari, J. Tessarolo, S. Quici, L. Armelao, M. Rancan A Cu(II) metallocycle for the reversible self-assembly of coordination-driven polyrotaxane-like architectures Dalton Trans., 2018, 47, 12079.

C. Mortalò, E. Rebollo, S. Escolástico, S. Deambrosis, K. Haas-Santob, M. Rancan, R. Dittmeyer, L. Armelao, M. Fabrizio Enhanced sulfur tolerance of BaCe_0.65Zr_0.20Y_0.15O_3-δ-Ce_0.85Gd_0.15O_2-δ composite for hydrogen separation membranes J. Memb. Sci., 2018, 564, 123.

L. Armelao, D. Belli Dell’Amico, G. Bottaro, L. Bellucci, L. Labella, F. Marchetti, C. A. Mattei, F. Mian, F. Pineider, G. Poneti, S. Samaritani 1D hetero-bimetallic regularly alternated 4f–3d coordination polymers based on N-oxide-4,4’-bipyridine (bipyMO) as a linker: photoluminescence and magnetic properties Dalton Trans. 2018, 47, 8337.

N. Comisso, L. Armelao, S. Cattarin, P. Guerriero, L. Mattarozzi, M. Musiani, M. Rancan, L. Vazquez-Gomez, E. Verlato Porous oxide electrocatalysts for oxygen evolution reaction prepared through a combination of hydrogen bubble templated deposition, oxidation and galvanic displacement steps Electrochim. Acta., 2018, 273, 454.

S. Barison, S. Fasolin, S. Boldrini, A. Ferrario, M. Romano, F. Montagner, S.M. Deambrosis, M. Fabrizio, L. Armelao PdAg/alumina membranes prepared by high power impulse magnetron sputtering for hydrogen separation Int. J. Hydr. Ener., 2018, 43, 7982.

S. Fasolin, S. Barison, S. Boldrini, A. Ferrario, E. Miorin, M. Fabrizio, M. Romano, L. Armelao Hydrogen separation by thin vanadium-based multi-layered membranes Int. J. Hydr. Ener., 2018, 43, 3235.

A. Privitera, M. Righetto, M. De Bastiani, F. Carraro, M. Rancan, L. Armelao, G. Granozzi, R. Bozio, L. Franco Hybrid organic/inorganic perovskites-polymer nanocomposites: towards the enhancement of structural and electrical properties , J. Phys. Chem. Lett., 2017, 8, 5981 5986.

N. Comisso, L. Armelao, S. Cattarin, P. Guerriero, L. Mattarozzi, M. Musiani, M. Rancan, L. Vázquez-Gómez, E. Verlato Preparation of porous oxide layers by oxygen bubble templated anodic deposition followed by galvanic displacement, Electrochim. Acta, 2017, 253, 11.

A. Pappacena, M. Rancan, L. Armelao, J. Llorca, W. Ge, B. Ye, A. Lucotti, A. Trovarelli, M. Boaro New Insights into the Dynamics That Control the Activity of Ceria–Zirconia Solid Solutions in Thermochemical Water Splitting Cycles, J. Phys. Chem. C., 2017, 121, 17746.

F. Mian, G. Bottaro, M. Rancan, L. Pezzato, V. Gombac, P. Fornasiero, L. Armelao Bi₁₂O₁₇Cl₂/(BiO)₂CO₃ Nanocomposite Materials for Pollutant Adsorption and Degradation: Modulation of the Functional Properties by Composition Tailoring, ACS Omega, 2017, 2, 6298.

L. Armelao, A. Carlotto, F. Mian, J. Tessarolo, G. Bottaro, M. Rancan Easy but not straightforward: base and solvent effect on the synthesis of luminescent europium 1,3-di(thien-2-yl)propane-1,3-dionate coordination complexes, Can. J. Chem., 2017, 95, 1183.

L. Armelao, D. Belli Dell’Amico, L. Bellucci, G. Bottaro, L. Di Bari , L. Labella , F. Marchetti, S. Samaritani , F. Zinna, Circularly Polarized Luminescence of Silica-Grafted Europium Chiral Derivatives Prepared through a Sequential Functionalization, Inorg. Chem., 2017, 56, 7010.

F. Rizzo, F. Polo, G. Bottaro, S. Fantacci, S. Antonello, L. Armelao, S. Quici, F. Maran, From Blue to Green: Fine-Tuning of Photoluminescence and Electrochemiluminescence in Bifunctional Organic Dyes, J. Am. Chem. Soc., 2017, 139, 2060.

J. Tessarolo, A. Venzo, G. Bottaro, L. Armelao, M. Rancan, Hampered Subcomponent Self-Assembly Leads to an Aminal Ligand: Reactivity with Silver(I) and Copper(II), Eur. J. Inorg. Chem, 2017, 30.